Separation of propylene and propane with a microporous metal–organic framework via equilibrium-kinetic synergetic effect

Adsorption separation of olefin and paraffin can greatly lower the energy consumption associated with the currently utilized distillation technique but remains a great challenge. Herein, we report the efficient separation of propylene (C₃H₆) and propane (C₃H₈) in a phosphate anion-functionalized metal–organic framework (MOF) ZnAtzPO₄ by synergetic effect of equilibrium and kinetics. The material features periodically expanded and contracted apertures decorated with electronegative groups, offering eligible pore shape and pore chemistry to effectively trap C₃H₆ under moderate isosteric heat of adsorption (27.5 kJ mol⁻¹) while obstruct the diffusion of C₃H₈. It simultaneously combines excellent thermodynamic selectivity (uptake ratio of 1.71) and kinetic selectivity (~31) for C₃H₆/C₃H₈ separation, meanwhile can be easily regenerated. Breakthrough experiment for C₃H₆/C₃H₈ gas mixture was conducted and confirmed the outstanding separation capability of ZnAtzPO₄. The equilibrium and kinetics cooperative C₃H₆/C₃H₈ adsorption separation was for the first time found in anion-functionalized MOFs, and further confirmed by computational studies.     

SURFACE CARBURIZATION OF TiAl BASED ALLOY

ＳＵＲＦＡＣＥＣＡＲＢＵＲＩＺＡＴＩＯＮＯＦＴｉＡｌＢＡＳＥＤＡＬＬＯＹ￥Ｈｕａｎｇ，Ｂａｉｙｕｎ；Ｈｅ，Ｙｕｅｈｕｉ；Ｑｕ，Ｘｕａｎｈｕｉ；Ｋｏｎｇ，Ｇａｏｎｉｎｇ（ＰｏｗｄｅｒＭｅｔａｌｌｕｒｇｙＲｅｓｅａｒｃｈＩｎｓｔｉｔｕｔｅ，Ｃｅｎｔｒａｌ...     

稀土和镁对热浸镀铝液和镀层组织的影响

研究了热浸镀铝液中添加微量稀土和镁对铝液质量和镀铝层厚度的影响及镀铝层的表面和第二相的形貌。结果表明，微量稀土改善了铝液的质量和镀层的组织，而微量镁有损铝液质量和镀层组织。     

碳热法合成具有蓝光发射特性的氧化镓纳米线、纳米带和纳米片

利用碳纳米管通过碳热法合成了氧化镓纳米线、纳米带和纳米片。采用扫描电镜和透射电镜对其进行了形态和结构表征。合成的氧化镓纳米结构是单晶体。室温光致发光谱分析发现，氧化镓纳米晶在蓝光区域487nm处产生明显的发射峰。     

W18Cr4V高速钢激光相变强化层的残余应力

利用Ｘ射线衍射法对Ｗ１８Ｃｒ４Ｖ高速钢激光相变强化层的残余应力进行了测定和分析。试验结果表明，相变强化层表面的残余应力为压应力，内部为拉应力，近似按正弦函数分布。其大小和分布状态随工艺参数的变化而改变。当改变工艺参数使表面熔化时，表面为拉应力。     

EFFECTS OF TWO－STEP HEAT－TREATMENT ON MICROSTRUCTURE AND PROPERTIES OF TiAl INTERMETALLICS

ＥＦＦＥＣＴＳＯＦＴＷＯ－ＳＴＥＰＨＥＡＴ－ＴＲＥＡＴＭＥＮＴＯＮＭＩＣＲＯＳＴＲＵＣＴＵＲＥＡＮＤＰＲＯＰＥＲＴＩＥＳＯＦＴｉＡｌＩＮＴＥＲＭＥＴＡＬＬＩＣＳ￥Ｋｏｎｇ，Ｇａｏｎｉｎｇ；Ｈｕａｎｇ，Ｂａｉｙｕｎ；Ｑｕ，Ｘｕａｎｈｕｉ；Ｌｅｉ，Ｃｈａ...     

高铝锌基合金直齿圆锥齿轮的挤压铸造工艺

利用挤压铸造技术生产高铝锌基合金直齿圆锥齿轮，齿面精度能够得到保证。适用于工作环境较好，载荷不是很大条件下的高铝锌基合金直齿圆锥齿轮，可减少设备投资、减少工序工时，从而大大降低生产成本，具有很高的经济效益和社会效益。     

炼油厂酮苯装置空冷器腐蚀原因分析

炼厂酮苯装置空冷器因空冷管束腐蚀穿孔被迫停工检修，经取样分析和现场调查，得出结论：溶解氧含量偏高，设备本身存在震动，无盐水质量不稳定及空冷管束选材不当是造成空冷器管束腐蚀穿孔的主要原因，提出有效大的防腐措施。     

对学术权力的再审视

近年来 ,有的学者对学术权力进行了重新界定 ,提出新的看法。本文从新观点提出的依据、专用术语与普通用语的区别、历史的内涵、概念的定义等角度 ,对这些新观点进行了深入的分析 ,说明了新观点存在的误区 ,指出学术权力这个概念并未超出原来的意义     

A study of the passive films on chromium by capacitance measurement

Using capacitance measurement and Mott-Schottky analysis, the semiconducting properties of passive films formed on chromium within the passive potential range under different conditions were investigated. The study reveals a p-type behavior of the passive layers. Two semiconductive parameters, i.e., the acceptor density (N_A) and the flatband potential (E_FB), which are mainly related to composition and surface charges of the passive films, have been measured. The effect of film formation potential, passivation time, pH and composition of solutions on the parameters are discussed. N_A increases either with lowering film formation potentials or with prolonging passivation times. This is attributed to the transformation of a less hydrated oxide film into a more hydrated form. The changes of E_FB are discussed as a function of adsorptive anions and pH values of electrolyte solution.